Preheat the oven to 400°F (200°C).
Thinly slice the Yukon Gold potatoes using a mandoline or sharp knife.
Place the potato slices in cold water for 10 minutes to remove excess starch.
Drain thoroughly and pat completely dry with paper towels.
In a large bowl, toss potatoes with olive oil, garlic powder, thyme, salt, and black pepper.
Build the Potato Napoleon Stacks
Generously grease a jumbo muffin tin with cooking spray.
Layer potato slices in overlapping circles inside each muffin cup.
Sprinkle Gruyere and Parmesan cheese between every few layers.
Continue layering until each muffin cup is full.
Gently press the stacks down to compact them.